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conservation of energy : ウィキペディア英語版
conservation of energy

In physics, the law of conservation of energy states that the total energy of an isolated system remains constant—it is said to be ''conserved'' over time. Energy can be neither created nor be destroyed, but it transforms from one form to another, for instance chemical energy can be converted to kinetic energy in the explosion of a stick of dynamite.
A consequence of the law of conservation of energy is that a perpetual motion machine of the first kind cannot exist. That is to say, no system without an external energy supply can deliver an unlimited amount of energy to its surroundings.〔Planck, M. (1923/1927). ''Treatise on Thermodynamics'', third English edition translated by A. Ogg from the seventh German edition, Longmans, Green & Co., London, page 40.〕
==History==

Ancient philosophers as far back as Thales of Miletus  550 BCE had inklings of the conservation of some underlying substance of which everything is made. However, there is no particular reason to identify this with what we know today as "mass-energy" (for example, Thales thought it was water). Empedocles (490–430 BCE) wrote that in his universal system, composed of four roots (earth, air, water, fire), "nothing comes to be or perishes"; instead, these elements suffer continual rearrangement.
In 1638, Galileo published his analysis of several situations—including the celebrated "interrupted pendulum"—which can be described (in modern language) as conservatively converting potential energy to kinetic energy and back again.
It was Gottfried Wilhelm Leibniz during 1676–1689 who first attempted a mathematical formulation of the kind of energy which is connected with ''motion'' (kinetic energy). Leibniz noticed that in many mechanical systems (of several masses, ''mi'' each with velocity ''vi'' ),
:\sum_ m_i v_i^2
was conserved so long as the masses did not interact. He called this quantity the ''vis viva'' or ''living force'' of the system. The principle represents an accurate statement of the approximate conservation of kinetic energy in situations where there is no friction. Many physicists at that time, such as Newton, held that the conservation of momentum, which holds even in systems with friction, as defined by the momentum:
:\,\!\sum_ m_i v_i
was the conserved ''vis viva''. It was later shown that both quantities are conserved simultaneously, given the proper conditions such as an elastic collision.
Émilie du Châtelet (1706 – 1749) proposed and tested the hypothesis of the conservation of total energy, as distinct from momentum. Inspired by the theories of Gottfried Leibniz, she repeated and publicized an experiment originally devised by Willem 's Gravesande in which balls were dropped from different heights into a sheet of soft clay. Each ball's kinetic energy - as indicated by the quantity of material displaced - was shown to be proportional to the square of the velocity. The deformation of the clay was found to be directly proportional to the height the balls were dropped from, equal to the initial potential energy. Earlier workers, including Newton and Voltaire, had all believed that "energy" (so far as they understood the concept at all) was not distinct from momentum and therefore proportional to velocity. In classical physics the correct formula is E_k = \frac12 mv^2, where E_k is the kinetic energy of an object, m its mass and v its speed.) On this basis, Châtelet proposed that energy must always have the same dimensions in any form, which is necessary to be able to relate it in different forms (kinetic, potential, heat…).〔Hagengruber, Ruth, editor (2011) ''Émilie du Chatelet between Leibniz and Newton''. Springer. ISBN 978-94-007-2074-9.〕
Engineers such as John Smeaton, Peter Ewart, Carl Holtzmann, Gustave-Adolphe Hirn and Marc Seguin recognized that conservation of momentum alone was not adequate for practical calculation and made use of Leibniz's principle. The principle was also championed by some chemists such as William Hyde Wollaston. Academics such as John Playfair were quick to point out that kinetic energy is clearly not conserved. This is obvious to a modern analysis based on the second law of thermodynamics, but in the 18th and 19th centuries the fate of the lost energy was still unknown.
Gradually it came to be suspected that the heat inevitably generated by motion under friction was another form of ''vis viva''. In 1783, Antoine Lavoisier and Pierre-Simon Laplace reviewed the two competing theories of ''vis viva'' and caloric theory.〔Lavoisier, A.L. & Laplace, P.S. (1780) "Memoir on Heat", ''Académie Royale des Sciences'' pp. 4–355〕 Count Rumford's 1798 observations of heat generation during the boring of cannons added more weight to the view that mechanical motion could be converted into heat, and (as importantly) that the conversion was quantitative and could be predicted (allowing for a universal conversion constant between kinetic energy and heat). ''Vis viva'' then started to be known as ''energy'', after the term was first used in that sense by Thomas Young in 1807.
The recalibration of ''vis viva'' to
:\frac \sum_ m_i v_i^2
which can be understood as converting kinetic energy to work, was largely the result of Gaspard-Gustave Coriolis and Jean-Victor Poncelet over the period 1819–1839. The former called the quantity ''quantité de travail'' (quantity of work) and the latter, ''travail mécanique'' (mechanical work), and both championed its use in engineering calculation.
In a paper ''Über die Natur der Wärme''(German "On the Nature of Heat/Warmth"), published in the ''Zeitschrift für Physik'' in 1837, Karl Friedrich Mohr gave one of the earliest general statements of the doctrine of the conservation of energy in the words: "besides the 54 known chemical elements there is in the physical world one agent only, and this is called ''Kraft'' (or work ). It may appear, according to circumstances, as motion, chemical affinity, cohesion, electricity, light and magnetism; and from any one of these forms it can be transformed into any of the others."

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